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對于粉煤灰的作用機理和應用技術，多年來進行了大量的研究工作，取得了不少進展，這些進展對粉煤灰在混凝土中的應用起了一定的推動作用。如摻用的方法從等量替代水泥，發(fā)展到超摻法、代砂法以及與化學外加劑同時使用的雙摻法。對于粉煤灰的作用機理，從主要是火山灰質材料特性的作用(消耗了水泥水化時生成薄弱的，而且往往富集在過渡區(qū)的氫氧化鈣片狀結晶，由于水化緩慢，只在后期才生成少量C-S-H凝膠，填充于水泥水化生成物的間隙，使其更加密實)，逐步發(fā)展到分析它還具有形態(tài)效應、填充效應和微集料效應等。但無論哪一方面的研究成果，似乎都改變不了這樣一個事實：在混凝土中摻粉煤灰要降低混凝土的強度，包括28天齡期以后一段時間里的強度，其他性能當然也相應受到不同程度的影響，而且這些影響要隨著摻量的增大而加劇。這個事實始終禁錮著粉煤灰在混凝土中，尤其是結構混凝土中的摻量，而且似乎形成了這樣一種成見：摻用粉煤灰是以犧牲結構混凝土的品質為代價的。<br /> 了解混凝土的微結構的特性及其對性能的影響后，就可以更好地認識粉煤灰在混凝土中的作用。粉煤灰的主要作用可以包括以下幾方面：<br /> 1、粉煤灰延緩了水化速度，減小混凝土因水化熱引起的溫升，對防止混凝土產(chǎn)生溫度裂縫十分有利。<br /> 2、填充骨料顆粒的空隙并包裹它們形成潤滑層，由于粉煤灰的容重(表觀密度)只有水泥的2/3左右，而且粒形好(質量好的粉煤灰含大量玻璃微珠)，因此能填充得更密實，在水泥用量較少的混凝土里尤其顯著。<br /> 3、對水泥顆粒起物理分散作用，使其分布得更均勻。當混凝土水膠比較低時，水化緩慢的粉煤灰可以提供水分，使水泥水化得更充分。<br /> 4、粉煤灰和富集在骨料顆粒周圍的氫氧化鈣結晶發(fā)生火山灰反應，不僅生成具有膠凝性質的產(chǎn)物(與水泥中硅酸鹽的水化產(chǎn)物相同)，而且加強了薄弱的過渡區(qū)，對改善混凝土的各項性能有顯著作用。</p> <p> </p> </p> </div> <div id="22kymga" class="pre-next"> <p><a href="/hydt/704.html">工業(yè)廢渣應該如何利用？</a></a></p> <p><a 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